I’m afraid that Toon Link is definitely out of his league in this battle. Samus is a master at long range fighting and she can negate Toon Link’s array of arrows with her arm cannon. In a close fight, Samus has superior speed and strength so she can just snatch Toon Link’s sword away and quickly defeat him. Samus isn’t one of Super Smash’s All Stars for nothing! Samus wins.